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Spectroscopy - An interdisciplinary integral description of spectroscopy from UV to NMR

Peter M. Skrabal

 

Verlag vdf Hochschulverlag AG, 2012

ISBN 9783728133854 , 354 Seiten

Format PDF, OL

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34,99 EUR


 

Cover

1

Dedication

3

Imprint

6

Preface

7

Foreword

9

Content

11

1 Introduction

13

1.1 Definitions and Systematics

13

1.2 Structure_Property Relations, Synthesis, and Process Planning

14

1.3 Development of Computers, Dynamics of Analytical Methods, and Process Control

18

1.4 Economic Significance of Analytical Methods

21

1.5 On the Conception of the Book

24

2 The Electromagnetic Spectrum

27

2.1 Its Regions and Present-Day Comprehension

27

2.2 The Instrumentation

33

3 The Absorption Processes and their Energies

43

3.1 The UV and Visible Region

45

3.2 The IR and Near IR (NIR) Region

54

3.3 The ESR Region

62

3.4 The NMR Region

71

3.5 A Comparative View

97

4 The Absorption Intensities: Prerequisites and Consequences

107

4.1 The UV and Visible Region

108

4.2 The IR and Near IR (NIR) Region

117

4.3 The ESR Region

122

4.4 The NMR Region

124

4.5 A Comparative View

136

5 Spectroscopy of Analytes in the four Phases

143

5.1 The Gas Phase

144

5.2 The Liquid Phase

145

5.3 Liquid Crystalline Phases

148

5.4 Solid-State Phases

151

5.5 Sample Preparation and Sample Purity

169

5.6 Internal and External Standards

177

6 The Measuring Techniques: CW and FT Spectroscopy

181

6.1 CW Spectroscopy

181

6.2 FT Spectroscopy

185

7 Spectroscopy in Two and Three Dimensions

199

7.1 1D Pulse Sequences in NMR Spectroscopy

200

7.2 Two-Dimensional (2D) and Three-Dimensional (3D)Spectroscopy

210

8 Application Areas and Limits

219

8.1 Structure Analyses

220

8.1.1 The Positions of Absorption Bands

221

8.1.2 Scalar Couplings, NOEs, and Relaxation Times

251

8.1.3 Solid-State Spectroscopy

267

8.1.4 Two- and Three-Dimensional Spectroscopy

277

8.2 Concentration and Kinetic Measurements

283

8.3 Dynamic Aspects

296

8.4 Diffusion Measurements and Imaging Spectroscopy

306

8.5 Opt(r)odes and Sensors, Tandem or Combined Methods

317

8.6 Chemometry

320

9 The Communication of Spectroscopic Data

323

10 Literature

329

10.1 A Selection of Textbooks and Standard Works

329

10.2 My Favorite Books

330

Addendum

331

Acronym, Name, and Keyword Index

337